{"id":994,"date":"2026-07-01T07:10:00","date_gmt":"2026-07-01T13:10:00","guid":{"rendered":"https:\/\/revistaece.dataware.cloud\/?p=994"},"modified":"2026-06-03T09:48:36","modified_gmt":"2026-06-03T15:48:36","slug":"materiales-ceramicos-pequenos-cambios-grandes-diferencias","status":"publish","type":"post","link":"https:\/\/revistaece.dataware.cloud\/?p=994","title":{"rendered":"Materiales cer\u00e1micos: Peque\u00f1os cambios, grandes diferencias"},"content":{"rendered":"\n

Mata L\u00f3pez Diana Laura1<\/sup>, G\u00f3mez Garc\u00eda Jos\u00e9 Francisco2<\/sup><\/p>\n\n\n\n

\"\"<\/figure><\/div>\n\n\n\n

Fechas de recepci\u00f3n: <\/strong>15-3-2026<\/p>\n\n\n\n

Fechas de aceptaci\u00f3n: <\/strong>14-4-2026<\/p>\n\n\n\n

Qu\u00edmica\/Epistemolog\u00eda social<\/strong> <\/strong><\/strong>
<\/strong><\/p>\n\n\n\n

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DOI: <\/strong>https:\/\/doi.org\/10.64121\/rece.2026V5.mg39<\/div><\/a><\/div><\/div>\n\n\n\n
PDF<\/div><\/a><\/div><\/div>\n<\/div><\/div>\n\n\n\n

Cuando escuchamos la palabra \u201ccer\u00e1mico\u201d probablemente lo primero en lo que pensamos es en la vajilla cara de la casa, s\u00ed, esa que solo utilizamos en ocasiones especiales y en d\u00edas festivos. Sin embargo, los cer\u00e1micos no solo se refieren a este tipo de materiales, por ello es necesario explicar qu\u00e9 es un cer\u00e1mico y hablar brevemente de su historia, as\u00ed como su relevancia en la vida cotidiana como en la ciencia.<\/p>\n\n\n\n

Los materiales cer\u00e1micos, en realidad, se refieren a los s\u00f3lidos inorg\u00e1nicos, que pueden estar formados por elementos met\u00e1licos y no met\u00e1licos unidos por enlaces i\u00f3nicos y\/o covalentes. Estos materiales se solidifican al calentarlos, y sus caracter\u00edsticas m\u00e1s relevantes son su nula conducci\u00f3n el\u00e9ctrica y t\u00e9rmica, su estabilidad a las altas temperaturas y a la corrosi\u00f3n, as\u00ed como su gran fragilidad y dureza. La palabra cer\u00e1mico proviene del griego \u03ba\u03ad\u03c1\u03b1\u03bc\u03bf\u03c2 (k\u00e9ramos) y significa \u201ctierra cocida\u201d, ya que estos materiales fueron identificados por primera vez como parte del suelo (barro y arcilla, principalmente) y sus primeros usos datan del a\u00f1o 23,000 A. C. Sin embargo, las primeras piezas de porcelana son de hace 3,000 a\u00f1os [Cu\u00e9llar-Herrera L.G., et al.<\/em>, 2023].<\/p>\n\n\n\n

Los materiales cer\u00e1micos son de gran importancia debido a su versatilidad de aplicaciones: desde materiales de construcci\u00f3n, vajillas y arcillas hasta pr\u00f3tesis dentales y componentes tecnol\u00f3gicos, pues su alta estabilidad en diferentes condiciones f\u00edsicas y qu\u00edmicas ha permitido que estos materiales sean empleados en una gran variedad de ramas, desde la ciencia hasta la ingenier\u00eda.<\/p>\n\n\n\n

El principal m\u00e9todo de s\u00edntesis de cer\u00e1micos es por estado s\u00f3lido convencional, que se basa en la molienda de las materias primas y su posterior calentamiento a temperaturas superiores a 600 \u00baC.<\/p>\n\n\n\n

Sin embargo, tambi\u00e9n pueden emplearse otros m\u00e9todos. Por ejemplo: de piedras se obtiene sulfuro de calcio hidratado y carbonato de calcio (CaSO4<\/sub>\u22192H2<\/sub>O y CaCO3<\/sub>) que, al calcinarse, forman yeso de Par\u00eds (CaSO4<\/sub>, sulfato de calcio) y cal viva (CaO, \u00f3xido de calcio); a la cal viva se le a\u00f1ade agua para formar un polvo fino de hidr\u00f3xido de calcio (Ca(OH)2<\/sub>); al a\u00f1adir agua al hidr\u00f3xido y sulfato de calcio, se comienza a modificar sus propiedades f\u00edsicas debido a la hidrataci\u00f3n y crecimiento de los granos que forman una suspensi\u00f3n de los s\u00f3lidos (mezcla heterog\u00e9nea donde part\u00edculas s\u00f3lidas no se disuelven en un l\u00edquido) que, poco a poco, se va volviendo espesa; a este proceso se le conoce como fraguado (gel donde las estructuras est\u00e1n desordenadas); este, al dejarse al sol y absorber di\u00f3xido de carbono (CO2<\/sub>), comienza a solidificarse en el proceso conocido como endurecimiento (las estructuras comienzan a ordenarse formando s\u00f3lidos cristalinos), donde finalmente se obtiene el cemento (Ecuaci\u00f3n 1) [Ochoa, R., Flores, E. 1994].<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

Ecuaci\u00f3n 1. Reacciones qu\u00edmicas del proceso de formaci\u00f3n de cemento.<\/p>\n\n\n\n

La variedad de estructuras y composici\u00f3n son las principales caracter\u00edsticas que vuelven interesantes y vers\u00e1tiles este tipo de materiales, ya que sus propiedades pueden ser modificadas al a\u00f1adir peque\u00f1as cantidades de otro compuesto; por ejemplo, se puede modificar su conductividad el\u00e9ctrica para obtener cer\u00e1micos semiconductores: estos est\u00e1n dise\u00f1ados para tener conductividad el\u00e9ctrica controlada en funci\u00f3n de la temperatura, y una de sus aplicaciones se ha encontrado en el tratamiento de aguas residuales [Hern\u00e1ndez Ram\u00edrez, A., & Torres Guerra, L. M., 2003].<\/p>\n\n\n\n

Su principal clasificaci\u00f3n es en cer\u00e1micos tradicionales (naturales y abundantes, como arcillas y porcelanas usados como materiales de construcci\u00f3n o loza de cocina, principalmente) y cer\u00e1micos avanzados, donde sus propiedades estructurales, mec\u00e1nicas, magn\u00e9ticas, electr\u00f3nicas, i\u00f3nicas, \u00f3pticas, densidad, conductividad t\u00e9rmica, dureza, resistencia y estabilidad han sido modificadas para que tengan un uso espec\u00edfico; por ejemplo: abrasivos, sistemas de almacenamiento de datos, dispositivos de almacenamiento de energ\u00eda, pr\u00f3tesis, implantes, materiales de laboratorio, pigmentos, materiales fluorescentes e incluso l\u00e1ser de estado s\u00f3lido. Dentro de los cer\u00e1micos avanzados, los conformados por \u00f3xidos met\u00e1licos han destacado en biomateriales debido a su microestructura homog\u00e9nea, donde sus principales aplicaciones se encuentran en reparaciones dentales, siendo una opci\u00f3n m\u00e1s sana para la sustituci\u00f3n de amalgamas met\u00e1licas, que anteriormente eran de mercurio, un metal t\u00f3xico para los seres vivos que se va acumulando en diferentes \u00f3rganos, causando da\u00f1os irreversibles en la salud. Estos son considerados biomateriales avanzados que han sido empleados debido a su compatibilidad con el cuerpo humano.<\/p>\n\n\n\n

El primer registro de cer\u00e1micos empleados en odontolog\u00eda es de 1717, cuando el bioqu\u00edmico franc\u00e9s Pierre Fauchardse realiz\u00f3 un puente removible de porcelana, y desde entonces este material ha sido usado por dentistas para la reparaci\u00f3n de muelas, sustituci\u00f3n de dientes y confecci\u00f3n de coronas. Dentro de los materiales cer\u00e1micos combinados, los que mayor empleo tienen en biomateriales son: los cer\u00f3meros (materiales inorg\u00e1nicos con micropart\u00edculas de cer\u00e1micos y relleno intersticial org\u00e1nico en su matriz), los ion\u00f3meros de vidrio (contienen pol\u00edmeros y cer\u00e1micos en diferentes proporciones) y los cer\u00e1micos de hidroxiapatita poliuretano, que han sido los m\u00e1s relevantes en esta rama, pues al estar compuestos del mismo material que los huesos (hidroxiapatita) permite la regeneraci\u00f3n \u00f3sea [Rasc\u00f3n, A. N., et al.<\/em> 2012].<\/p>\n\n\n\n

Uno de los cer\u00e1micos que m\u00e1s se ha estudiado es la zirconia (di\u00f3xido de zirconio, ZrO2<\/sub>) debido a sus propiedades mec\u00e1nicas, su alta estabilidad y su poca degradaci\u00f3n hidrot\u00e9rmica, que han permitido su empleo en coronas, puentes y pr\u00f3tesis [Tabares, J.A. 2012]. Sin embargo, modificar su estructura con alg\u00fan otro metal ha permitido que la zirconia pueda ser empleada como electrolito en bater\u00edas de combustible, sensores de ox\u00edgeno o como barrera t\u00e9rmica.<\/p>\n\n\n\n

El m\u00e1s conocido es la zirconia estabilizada con itria (YSZ) (, donde el itrio se encuentra en cantidades del 3 al 8 % en fracci\u00f3n mol) que presenta una alta conductividad i\u00f3nica a temperaturas elevadas, lo que le permite funcionar como un electrolito s\u00f3lido, es decir, que permite que los iones ox\u00edgeno se muevan dentro de su estructura, sin permitir el paso de los electrones. Tambi\u00e9n se ha empleado como electrodos para bater\u00edas de combustibles de \u00f3xidos s\u00f3lidos (SOFC), sensores de ox\u00edgeno, material refractario y recubrimiento met\u00e1lico, debido a su baja corrosi\u00f3n, poco desgaste y bajo coeficiente de conductividad t\u00e9rmica [Fern\u00e1ndez-Gonz\u00e1lez, R., et al.<\/em> 2014].<\/p>\n\n\n\n

Esta es solo una peque\u00f1a visi\u00f3n de todo lo que se puede lograr empleando materiales cer\u00e1micos en diferentes ramas, donde destacan por su alta estabilidad en diferentes condiciones qu\u00edmicas, mec\u00e1nicas y t\u00e9rmicas, por lo que su estudio seguir\u00e1 vigente a trav\u00e9s de los a\u00f1os, pues permite obtener desde materiales con aplicaciones m\u00e9dicas hasta electr\u00f3nicas, debido a la facilidad con la que se pueden modificar tanto su composici\u00f3n como sus propiedades estructurales, dando opciones m\u00e1s viables o menos t\u00f3xicas, como en el caso de las amalgamas de mercurio.<\/p>\n\n\n\n

Palabras clave:<\/strong> cer\u00e1micos, cer\u00e1micos tradicionales, cer\u00e1micos avanzados, biomateriales, YSZ.<\/p>\n\n\n\n

Autores<\/strong><\/h3>\n\n\n\n

1 <\/sup>Diana Laura Mata L\u00f3pez:<\/strong> Maestra en Ciencias por la UNAM, interesada en el desarrollo de nuevos materiales con alta conductividad, eficientes y seguros en el desarrollo de nuevas bater\u00edas. Facultad de Qu\u00edmica, UNAM. (Autor corresponsal).<\/strong> Contacto:<\/strong> screamer_btr14@comunidad.unam.mx ORCID: <\/strong>0009-0007-9355-2822<\/p>\n\n\n\n

2 <\/sup>Jos\u00e9 Francisco G\u00f3mez Garc\u00eda:<\/strong> Doctor en Ciencias por la UNAM, dedicado a la s\u00edntesis y caracterizaci\u00f3n de materiales cer\u00e1micos con aplicaciones en dispositivos electroqu\u00edmicos a altas temperaturas o tecnolog\u00edas dirigidas a energ\u00edas limpias, modulando sus propiedades f\u00edsicas mediante la modificaci\u00f3n de las propiedades estructurales y cristalinas de los materiales. Facultad de Qu\u00edmica, UNAM.<\/strong> Contacto:<\/strong> jfrancisco@comunidad.unam.mx ORCID: <\/strong>0000-0003-1309-7190<\/p>\n\n\n\n

Agradecimientos:<\/strong><\/h3>\n\n\n\n

Al SECIHTI por la beca otorgada: 1139636<\/p>\n\n\n\n

Al financiamiento de proyectos DGAPA-UNAM: IA-107123 e IN-212025<\/p>\n\n\n\n

Referencias bibliogr\u00e1ficas<\/strong><\/h3>\n\n\n\n

Cu\u00e9llar-Herrera L.G., Raya-Col\u00edn J.A., Carrera-Figueiras C., Ortiz-Landeros J. (2023). Los materiales cer\u00e1micos: definici\u00f3n, clasificaci\u00f3n y breve descripci\u00f3n de su estructura y propiedades. Revista Materiales Avanzados<\/em>. 39, 114-123. <\/strong>DOI: 10.22201\/iim.rma.2023.3.19<\/strong><\/p>\n\n\n\n

Fern\u00e1ndez-Gonz\u00e1lez, R., Molina, T., Savvin, S., Moreno, R., Makradi, A., & N\u00fa\u00f1ez, P. (2014). Fabrication and electrical characterization of several YSZ tapes for SOFC applications. Ceramics International<\/em>, 40<\/em>(9), 14253-14259. DOI: https:\/\/doi.org\/10.1016\/j.ceramint.2014.06.015<\/p>\n\n\n\n

Hern\u00e1ndez Ram\u00edrez, A., & Torres Guerra, L. M. (2003). Materiales cer\u00e1micos y luz solar: m\u00e9todo novedoso en tecnolog\u00edas de tratamiento de aguas residuales. Ciencia UANL<\/em>, 6<\/em>(4).<\/p>\n\n\n\n

Ochoa, R., Flores, E. (1994). Qu\u00edmica del cemento. Revista de qu\u00edmica<\/em>, 1<\/em>(1), 207-214.<\/p>\n\n\n\n

Rasc\u00f3n, A. N., Nev\u00e1rez Rasc\u00f3n, M. M., Bologna Molina, R. E., G\u00f3mez, E. S., Carre\u00f3n Burciaga, R. G., Palacio Gast\u00e9lum, M. G., … & Gonz\u00e1lez, R. G. (2012). Caracter\u00edsticas de los materiales cer\u00e1micos empleados en la pr\u00e1ctica odontol\u00f3gica actual. Revista ADM<\/em>, 69<\/em>(4).<\/p>\n\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

Mata L\u00f3pez Diana Laura1, G\u00f3mez Garc\u00eda Jos\u00e9 Francisco2 Fechas de recepci\u00f3n: 15-3-2026 Fechas de aceptaci\u00f3n: 14-4-2026 Qu\u00edmica\/Epistemolog\u00eda social Cuando escuchamos […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_uag_custom_page_level_css":"","site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center 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